The 1,3 migration of a methyl group in reactions of the trisyl iodide (Me3Si)3CSi(CD3)2I and related iodides with silver salts in 2,2,2-trifluoroethanol. Refinement of the mechanism-Reference-Cited by-同舟云学术

The 1,3 migration of a methyl group in reactions of the trisyl iodide (Me3Si)3CSi(CD3)2I and related iodides with silver salts in 2,2,2-trifluoroethanol. Refinement of the mechanism

Published:2002 Issue:8 Volume: Page:1418
ISSN:1472-779X
Container-title:Journal of the Chemical Society, Perkin Transactions 2
language:en
Short-container-title:J. Chem. Soc., Perkin Trans. 2

Author:

Eaborn Colin,Happer Duncan A. R.,Black Jarrett R.,Garrity Philip M.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2002/P2/B204130H

Reference7 articles.

1. The reactions of [tris(trimethylsilyl)methyl]silicon halides and hydrides with electrophilic reagents

2. Unusual mechanistic pathways. The novel chemistry of compounds with tris(trimethylsilyl)methyl or related ligands on siliconElectronic supplementary information (ESI) available: a complete list of the author's publications, with titles, on compounds with trisyl or related ligands on silicon (and for comparison, on germanium or tin) or species containing trisyl-type groups not on a metal or metalloid. See http://www.rsc.org/suppdata/dt/b1/b106509m/

3. The reactions of tris(trimethylsilyl)silicon iodides and hydrides with iodine monochloride

4. Predominance of unrearranged products in the reactions of the iodide (Me3Si)3CSi(CD3)2I with silver salts, and its mechanistic implications

5. 1,3-Si-to-Si migration of a methyl group. Ratio of rearranged and unrearranged products in the reactions of the iodide (Me3Si)3CSi(CD3)2I with ICI

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1. Silylium Ion to Silylium Ion Rearrangement Caused by 1,3-Methyl Migration;Chemistry Letters;2004-01

2. The Reaction of Highly Hindered Silicon Halides with Nucleophiles;Australian Journal of Chemistry;2004