Mono- and di-cationic hydrido boron compounds-Reference-Cited by-同舟云学术

Mono- and di-cationic hydrido boron compounds

Published:2015 Issue:32 Volume:44 Page:14359-14367
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ghadwal Rajendra S.¹²³⁴⁵^ORCID,Schürmann Christian J.⁵⁶⁴,Andrada Diego M.⁷⁸⁹⁴,Frenking Gernot⁷⁸⁹⁴

Affiliation:

1. Institut für Anorganische Chemie

2. Universität Bielefeld

3. 33615 Bielefeld

4. Germany

5. Institut für Anorganische Chemie der Georg-August-Universität Göttingen

6. 37077 Göttingen

7. Fachbereich Chemie

8. Philipps-Universität Marburg

9. 35032 Marburg

Abstract

Stable mono- and di-cationic hydrido boron compounds featuring CH₂BH₂(μ-H)BH₂CH₂ and CH₂BH(μ-H)₂BHCH₂ cores are readily accessible by dehydrogenative hydride abstractions. NBO calculations revealed the occurrence of two B–H–B 3c–2e bonds in the HB(μ-H)₂BH moiety of di-cations (7 and 8), where 43% is located at the H bridges and ∼28% at each boron atom.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02237A

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