Open-cage silsesquioxane necklace polymers having closed-cage silsesquioxane pendants
Author:
Affiliation:
1. Faculty of Molecular Chemistry and Engineering
2. Graduate School of Science and Technology
3. Kyoto Institute of Technology
4. Kyoto 606-8585
5. Japan
Abstract
A novel POSS monomer design has been proposed; a closed-cage POSS was tethered to an open-cage POSS, and the remaining two functional groups were employed for polymerization. The thermal and optical properties of the obtained main-chain type POSS polymers can be widely tuned by the substituents at the corners of the POSSs.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2018/PY/C8PY00758F
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