A multimetallic iron(ii)–lithium complex as a catalyst for ε-caprolactone polymerization-Reference-Cited by-同舟云学术

A multimetallic iron(ii)–lithium complex as a catalyst for ε-caprolactone polymerization

Published:2016 Issue:40 Volume:45 Page:15779-15782
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Geng Chao¹²³⁴⁵,Peng Ying¹²³⁴⁵,Wang Lijuan¹²³⁴⁵,Roesky Herbert W.⁶⁷⁸⁹,Liu Kaipeng¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Fine Chemicals

2. School of Pharmaceutical Science and Technology

3. Dalian University of Technology

4. Dalian 116024

5. P. R. China

6. Institut für Anorganische Chemie

7. Universität Göttingen

8. 37077 Göttingen

9. Germany

Abstract

Treatment of the lithium salt of β-ketimine with FeCl₂(THF)_1.5 in the presence of LiN(SiMe₃)₂ and water affords the multimetallic iron(ii)–lithium complex 1, [(L^Me)₂Fe]₃Li₂O [where L^Me = MeC(O)CHC(NMe)Me].

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00078A

Reference27 articles.

1. Synthesis of polycaprolactone: a review

2. Metal catalysts for ε-caprolactone polymerisation

3. Mechanistic Comparison of Cyclic Ester Polymerizations by Novel Iron(III)−Alkoxide Complexes: Single vs Multiple Site Catalysis

4. A well-defined iron(ii) alkoxide initiator for the controlled polymerisation of lactide

5. Synthesis, structure of functionalized N-heterocyclic carbene complexes of Fe(II) and their catalytic activity for ring-opening polymerization of ε-caprolactone

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