Structures and bonding in [L]M(μ-CCR)2M[L] and [L]M(μ-RC4R)M[L]: requirements for C–C coupling
Author:
Affiliation:
1. Department of Inorganic and Physical Chemistry
2. Indian Institute of Science
3. Bangalore 560012
4. India
Abstract
We report the geometric and electronic structures of [L]M(μ-CCR)2M[L] and their C–C coupled products [L]M(μ-RC4R)M[L], considering selected elements from the main group, transition metals, actinides and lanthanides.
Funder
Indian Institute of Science
Science and Engineering Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04748D
Reference38 articles.
1. Novel Mechanism for Interesting C−C Coupling and Cleavage Reactions and Control of Thermodynamic Stability Involving [L2M(μ-CCR)2ML2] and [L2M(μ-RCC-CCR)ML2] Complexes (M = Ti, Zr; L = η5-C5H5, Cl, H; R = H, F, CN): A Theoretical Study1
2. Metallacyclocumulenes: A Theoretical Perspective on the Structure, Bonding, and Reactivity
3. Computational insights into carbon–carbon homocoupling reactions mediated by organolanthanide(iii) complexes
4. The reductive coupling of dinitrogen
5. Ab initiopseudopotentials for Hg through Rn
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