Mixing Li and Cs in the reduction of corannulene for the assembly of a cesium-capped sandwich with a hexanuclear heterometallic core-Reference-Cited by-同舟云学术

Mixing Li and Cs in the reduction of corannulene for the assembly of a cesium-capped sandwich with a hexanuclear heterometallic core

Published:2017 Issue:17 Volume:46 Page:5625-5630
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Spisak Sarah N.¹²³⁴⁵,Wei Zheng¹²³⁴⁵,Petrukhina Marina A.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University at Albany

3. State University of New York

4. Albany

5. USA

Abstract

In the first Li/Cs organometallic self-assembly, the tetrareduced corannulene decks are angled up to keep the highly-charged (Li₃Cs₃)⁶⁺ unit in between, with two external Cs⁺ ions capping the sandwich from outside.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04521A

Reference49 articles.

1. Palladium-Catalyzed C–H Activation Taken to the Limit. Flattening an Aromatic Bowl by Total Arylation

2. Trimethylsumanene: Enantioselective Synthesis, Substituent Effect on Bowl Structure, Inversion Energy, and Electron Conductivity

3. C20H4(C4F8)3: A Fluorine-Containing Annulated Corannulene that Is a Better Electron Acceptor Than C60

4. Syntheses and Properties of Buckybowls Bearing Electron-withdrawing Groups

5. Highly Curved Bowl-Shaped Fragments of Fullerenes: Synthesis, Structural Analysis, and Physical Properties

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