Choline chloride-promoted efficient solvent-free hydrogenation of biomass-derived levulinic acid to γ-valerolactone over Ru/C-Reference-Cited by-同舟云学术

Choline chloride-promoted efficient solvent-free hydrogenation of biomass-derived levulinic acid to γ-valerolactone over Ru/C

Published:2021 Issue:5 Volume:23 Page:1983-1988
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Liu Huai¹²³⁴⁵,Cao Xuejuan¹²³⁴⁵,Tang Xing¹²³⁴⁵^ORCID,Zeng Xianhai¹²³⁴⁵^ORCID,Sun Yong¹²³⁴⁵,Ke Xixian⁶⁷⁸⁵,Lin Lu¹²³⁴⁵

Affiliation:

1. Xiamen Key Laboratory of Clean and High-valued Applications for Biomass

2. College of Energy

3. Xiamen University

4. Xiamen 361102

5. China

6. Key Lab for Sport Shoes Upper Materials of Fujian Province (Fujian Huafeng New Material Co.

7. Ltd.)

8. Putian 351144

Abstract

The hydrogen bond between LA and ChCl boosted the solvent-free hydrogenation of LA over Ru/C by alleviating the adsorption of the carboxylic group and enhancing the adsorption of the acyl group of LA.

Funder

National Natural Science Foundation of China

Special Project for Research and Development in Key areas of Guangdong Province

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D1GC00100K

Reference37 articles.

1. Production of γ-valerolactone from lignocellulosic biomass for sustainable fuels and chemicals supply

2. Exploring the ruthenium catalysed synthesis of γ-valerolactone in alcohols and utilisation of mild solvent-free reaction conditions

3. Front Cover: Chemoenzymatic Halocyclization of γ,δ‐Unsaturated Carboxylic Acids and Alcohols (ChemSusChem 1/2020)

4. Efficient Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran over Fe2O3-Promoted MnO2 Catalyst

5. Ammonia borane enabled upgrading of biomass derivatives at room temperature

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