Rapid access to bicyclic δ-lactones via carbene-catalyzed activation and cascade reaction of unsaturated carboxylic esters-Reference-Cited by-同舟云学术

Rapid access to bicyclic δ-lactones via carbene-catalyzed activation and cascade reaction of unsaturated carboxylic esters

Published:2016 Issue:2 Volume:3 Page:145-149
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Fu Zhenqian¹²³⁴⁵,Wu Xingxing¹²³⁴⁵,Chi Yonggui Robin¹²³⁴⁵

Affiliation:

1. Division of Chemistry and Biological Chemistry

2. School of Physical and Mathematical Sciences

3. Nanyang Technological University

4. Singapore 637371

5. Singapore

Abstract

The carbene-catalyzed activation of α,β-unsaturated ester initiates a well-controlled cascade process for access to iridoid-type multi-cyclic lactones with high stereo-selectivities.

Funder

Ministry of Education - Singapore

Nanyang Technological University

National Research Foundation-Prime Minister's office, Republic of Singapore

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/QO/C5QO00348B

Reference88 articles.

1. Iridoids. A Review

2. Biological and pharmacological activity of naturally occurring iridoids and secoiridoids

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4. Naturally Occurring Iridoids and Secoiridoids. An Updated Review, Part 4

5. Iridoids from the roots of Valeriana jatamansi and their neuroprotective effects

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