Structural rationale for the chiral separation and migration order reversal of clenpenterol enantiomers in capillary electrophoresis using two different β-cyclodextrins-Reference-Cited by-同舟云学术

Structural rationale for the chiral separation and migration order reversal of clenpenterol enantiomers in capillary electrophoresis using two different β-cyclodextrins

Published:2017 Issue:41 Volume:19 Page:27935-27939
ISSN:1463-9076
Container-title:Phys. Chem. Chem. Phys.
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Salgado Antonio¹²³⁴⁵^ORCID,Tatunashvili Elene⁶⁷⁸⁹¹⁰,Gogolashvili Ann⁶⁷⁸⁹¹⁰,Chankvetadze Bezhan⁶⁷⁸⁹¹⁰,Gago Federico¹¹⁴⁵¹²^ORCID

Affiliation:

1. NMR Spectroscopy Centre (CERMN)

2. CAI Químicas

3. Faculty of Pharmacy

4. University of Alcalá

5. E-28805 Alcalá de Henares

6. Institute of Physical and Analytical Chemistry

7. School of Exact and Natural Sciences

8. Tbilisi State University

9. 0179 Tbilisi

10. Georgia

11. Department of Biomedical Sciences (Unidad Asociada IQM-CSIC) and Instituto de Investigación Química “Andrés M. del Río” (IQAR)

12. Spain

Abstract

The observed reversal of migration order of clenpenterol enantiomers in capillary electrophoresis runs was studied by NMR, molecular dynamics simulations and theoretical chemistry calculations.

Funder

Shota Rustaveli National Science Foundation

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP04761D

Reference25 articles.

1. Cyclodextrin Inclusion Compounds in Research and Industry

2. The Stability of Cyclodextrin Complexes in Solution