Substituent effects of the phenyl ring at different positions from the α-carbon of TEMPO-type nitroxide-Reference-Cited by-同舟云学术

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Substituent effects of the phenyl ring at different positions from the α-carbon of TEMPO-type nitroxide

Published:2022 Issue:40 Volume:20 Page:7956-7962
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Yamasaki Toshihide¹^ORCID,Matsuda Yuto¹,Munekane Masayuki¹,Sano Kohei¹^ORCID,Mukai Takahiro¹^ORCID

Affiliation:

1. Laboratory of Biophysical Chemistry, Kobe Pharmaceutical University, 4-19-1 Motoyamakita-machi, Higashinada-ku, Kobe 658-8558, Japan

Abstract

TEMPO-based nitroxides with different distances between the phenyl group and the C2 carbon were synthesized and their ESR, redox potential, reduction reactivity toward ascorbate, and computational geometry were evaluated.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB01589G

Reference15 articles.

1. The chemistry and biology of nitroxide compounds

2. Practical Aerobic Oxidations of Alcohols and Amines with Homogeneous Copper/TEMPO and Related Catalyst Systems

3. Nitroxide-mediated polymerization

4. Discovery and Exploitation of AZADO: The Highly Active Catalyst for Alcohol Oxidation

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