Effect of salt selection and molar ratio in molten salt synthesis of single-crystalline LiNiO2

Author:

van den Bergh Wessel1,Yao Rui1,Zhang Ruizhuo1ORCID,Kondrakov Aleksandr12,Janek Jürgen13ORCID,Brezesinski Torsten1ORCID

Affiliation:

1. Battery and Electrochemistry Laboratory (BELLA), Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Herrmann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

2. BASF SE, Carl-Bosch-Str. 38, 67056 Ludwigshafen, Germany

3. Institute of Physical Chemistry & Center for Materials Research (ZfM/LaMa), Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, 35392 Giessen, Germany

Abstract

Using experimental design, select molten salt conditions, which can produce well-ordered single-crystalline LiNiO2 particles, are modeled. This provides a synthetic guideline to future developments of molten-salt-derived single crystal NCMs.

Funder

BASF

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

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