Elusive 2H-1,2-oxasiletes through reactions of an isolable dialkylsilylene with diazocarbonyl compounds-Reference-Cited by-同舟云学术

Elusive 2H-1,2-oxasiletes through reactions of an isolable dialkylsilylene with diazocarbonyl compounds

Published:2015 Issue:36 Volume:13 Page:9471-9476
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Dong Zhaowen¹²³⁴⁵,Xiao Xu-Qiong¹²³⁴⁵,Li Zhifang¹²³⁴⁵,Lu Qiong¹²³⁴⁵,Lai Guoqiao¹²³⁴⁵,Kira Mitsuo¹²³⁴⁵

Affiliation:

1. Key Laboratory of Organosilicon Chemistry and Material Technology

2. Ministry of Education

3. Hangzhou Normal University

4. Hangzhou 310012

5. P. R. China

Abstract

The reactions of isolable dialkysilylene 1 with compounds 5 and 6 gave elusive silacycles, 2H-1,2-oxasiletes 2 and 3, respectively, with releasing dinitrogen. In contrast, six-membered cyclic diazo compound 8 was obtained in a good yield by the reaction of 1 with less reactive 7.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB01224D

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