Clean protocol for deoxygenation of epoxides to alkenes via catalytic hydrogenation using gold-Reference-Cited by-同舟云学术

Clean protocol for deoxygenation of epoxides to alkenes via catalytic hydrogenation using gold

Published:2021 Issue:1 Volume:11 Page:312-318
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Fiorio Jhonatan L.¹²³⁴⁵^ORCID,Rossi Liane M.¹²³⁴⁵^ORCID

Affiliation:

1. Departamento de Química Fundamental

2. Instituto de Química

3. Universidade de São Paulo

4. São Paulo

5. Brazil

Abstract

Au NP catalyst combined with triethylphosphite, P(OEt)₃, is remarkably more reactive than solely Au NPs for the selective deoxygenation of epoxides to alkenes.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Fundação de Amparo à Pesquisa do Estado de São Paulo

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Instituto Nacional de Ciência e Tecnologia de Catálise em Sistemas Moleculares e Nanoestruturados

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D0CY01695K

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4. Carbonylative, Catalytic Deoxygenation of 2,3-Disubstituted Epoxides with Inversion of Stereochemistry: An Alternative Alkene Isomerization Method

5. An efficient protocol for the eliminative deoxygenation of aliphatic and aromatic epoxides to olefins with polyphosphoric acid as a promoter

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