Pb2.28Ba1.72B10O19 featuring a three-dimensional B–O anionic network with edge-sharing [BO4] obtained under ambient pressure
Author:
Affiliation:
1. CAS Key Laboratory of Functional Materials and Devices for Special Environments
2. Xinjiang Technical Institute of Physics & Chemistry
3. CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices
4. Urumqi 830011
5. China
Abstract
The unique borate Pb2.28Ba1.72B10O19 containing a three-dimensional B–O anionic network with edge-sharing [BO4] was obtained under ambient pressure, featuring an extremely large B–B interatomic distance (dB–B) and small internal O–B–O angles (∠in(O–B–O)).
Funder
Youth Innovation Promotion Association of the Chinese Academy of Sciences
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/QI/D1QI00653C
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