Direct isoperfluoropropylation of arenediazonium salts with hexafluoropropylene
Author:
Affiliation:
1. Department of Chemistry
2. Shanghai University
3. Shanghai 200444
4. China
5. Key Laboratory of Organofluorine Chemistry
6. Shanghai Institute of Organic Chemistry
7. Chinese Academy of Sciences
8. Shanghai 200032
Abstract
Perfluoropropylene can be used directly for isoperfluoropropylation of arenediazonium salts in the presence of silver fluoride and cuprous iodide. A practical tandem diazotization and isoperfluoropropylation protocol was developed for aniline derivatives to generate isoperfluoropropylarenes with good functional-group compatibility.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/QO/C5QO00388A
Reference45 articles.
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2. K. Uneyama , Organofluorine Chemistry, Blackwell, Oxford, 2006
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4. Aromatic Trifluoromethylation with Metal Complexes
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