Tuning the hybridization and charge polarization in metal nanoparticles dispersed over Schiff base functionalized SBA-15 enhances CO2 capture and conversion to formic acid

Author:

Cherevotan Arjun12,Ray Bitan12ORCID,Yadav Anish12,Bagchi Debabrata12ORCID,Singh Ashutosh Kumar23ORCID,Riyaz Mohd12,Churipard Sathyapal R.12ORCID,Naral Vinay12,Kaur Komalpreet4,Gautam Ujjal K.4ORCID,Vinod Chathakudath P.5ORCID,Peter Sebastian C.12ORCID

Affiliation:

1. New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064, India

2. School of Advanced Materials, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064, India

3. Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064, India

4. Department of Chemical Sciences, Indian Institute of Science Education and Research, Mohali, Sector 81, Mohali, SAS Nagar, Punjab, 140306, India

5. Catalysis and Inorganic Chemistry Division, CSIR-National Chemical Laboratory, Pune 411008, India

Abstract

This work reports the development of metal nanoparticles dispersed over Schiff base functionalized SBA-15. Tuning the hybridization favours optimum CO2 capture and charge polarization at metal nanoparticles enhances the conversion of CO2 to formic acid.

Funder

Science and Engineering Research Board

Jawaharlal Nehru Centre for Advanced Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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