Influence of substituents in aryl groups on the structure, thermal transitions and electrorheological properties of zinc bis(diarylphosphate) hybrid polymers

Author:

Dębowski Maciej1ORCID,Guńka Piotr A.1ORCID,Żurawski Konrad1,Zybert Magdalena1ORCID,Modzelewska Beata1,Ostrowski Andrzej1ORCID,Zachara Janusz1ORCID,Florjańczyk Zbigniew1ORCID

Affiliation:

1. Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warszawa, Poland

Abstract

The structures and thermal and electrorheological properties of coordination polymers with the formula Zn[O2P(OC6H4R)2]3 [R = OMe, NO2 or C(O)OEt] are reported.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference38 articles.

1. B. P.Block , H. D.Gillman and P.Nannelli , The Synthesis and Characterization of the Poly(Metal Phosphinates). Technical report for The Office of Naval Research , 1977 . https://apps.dtic.mil/sti/pdfs/ADA041511.pdf , (accessed January 2022)

2. Hybrid Organic-Inorganic Materials Based on Organophosphorus Derivatives

3. M.Taddei and F.Costantino , Metal Phosphonates and Phosphinates , MDPI , Basel , 2020 , and the references therein

4. Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure, Transformations, and Applications

5. Tetrahedral-atom zincophosphate structures. Zinc diethyl phosphate, [Zn(O2P(OC2H5)2)2]x, a one-dimensional inorganic "polymer"

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