Mild access to planar-chiral ortho-condensed aromatic ferrocenes via gold(i)-catalyzed cycloisomerization of ortho-alkynylaryl ferrocenes-Reference-Cited by-同舟云学术

Mild access to planar-chiral ortho-condensed aromatic ferrocenes via gold(i)-catalyzed cycloisomerization of ortho-alkynylaryl ferrocenes

Published:2016 Issue:38 Volume:52 Page:6419-6422
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Urbano Antonio¹²³⁴⁵,Hernández-Torres Gloria¹²³⁴⁵,del Hoyo Ana M.¹²³⁴⁵,Martínez-Carrión Alicia¹²³⁴⁵,Carmen Carreño M.¹²³⁴⁵

Affiliation:

1. Departamento de Química Orgánica (Módulo 01)

2. Facultad de Ciencias

3. Universidad Autónoma de Madrid

4. Cantoblanco

5. 28049-Madrid

Abstract

An asymmetric gold(i)-catalyzed intramolecular hydroarylation of aquiral 2-alkynylaryl ferrocenes provides (R_p) planar-chiral ortho-condensed aromatic ferrocenes in high yield and enantioselectivity.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC02624A

Reference61 articles.

1. Chiral Ferrocenes in Asymmetric Catalysis, ed. L.-X. Dai and X.-L. Hou, Wiley-VCH, Weinheim, 2010

2. Enantioselective C–C and C–heteroatom bond forming reactions using chiral ferrocene catalysts

3. Ferrocene phosphane-heteroatom/carbon bidentate ligands in asymmetric catalysis

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