First π-linker featuring mercapto and isocyano anchoring groups within the same molecule: synthesis, heterobimetallic complexation and self-assembly on Au(111)

Author:

Applegate Jason C.1234,Okeowo Monisola K.1234,Erickson Nathan R.1234,Neal Brad M.1234,Berrie Cindy L.1234,Gerasimchuk Nikolay N.1564,Barybin Mikhail V.1234

Affiliation:

1. Department of Chemistry

2. The University of Kansas

3. Lawrence

4. USA

5. Missouri State University

6. Springfield

Abstract

Azulene is a convenient platform for accessing heterobimetallic complexes and self-assembled monolayers of a π-linker with asymmetric junctions.

Funder

Division of Chemistry

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference62 articles.

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2. M. V. Barybin , J. J.Meyers Jr and B. M.Neal, in Isocyanide Chemistry - Applications in Synthesis and Material Science, ed. Nenajdenko V., Wiley-VCH, Weinheim, 2012, pp. 493–529

3. M. Lasar and R. J.Angelici, in Modern Surface Organometallic Chemistry, ed. J.-M. Basset, R. Psaro, D. Roberto and R. Ugo, Wiley-VCH, Weinheim, 2009, pp. 513–556

4. Conduction mechanisms in biphenyl dithiol single-molecule junctions

5. The gold–sulfur interface at the nanoscale

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