From centrosymmetric to noncentrosymmetric: effect of the cation on the crystal structures and birefringence values of (NH4)n−2AE(PO2F2)n (AE = Mg, Sr and Ba; n = 2, 3 and 4)-Reference-Cited by-同舟云学术

From centrosymmetric to noncentrosymmetric: effect of the cation on the crystal structures and birefringence values of (NH4)n−2AE(PO2F2)n (AE = Mg, Sr and Ba; n = 2, 3 and 4)

Published:2021 Issue:29 Volume:50 Page:10206-10213
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Wenyao¹²³⁴⁵,Jin Wenqi¹²³⁴⁵,Cheng Meng¹²³⁴⁵,Zhang Ruonan¹²³⁴⁵,Yang Zhihua¹²³⁴⁵^ORCID,Pan Shilie¹²³⁴⁵^ORCID

Affiliation:

1. CAS Key Laboratory of Functional Materials and Devices for Special Environments; Xinjiang Technical Institute of Physics & Chemistry

2. CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices

3. Urumqi 830011

4. China

5. Center of Materials Science and Optoelectronics Engineering

Abstract

Four alkaline-earth metal difluorophosphates with different space groups were synthesized for the first time. The differences in arrangements of the (PO₂F₂) units lead to disparate optical anisotropy of the crystals.

Funder

National Natural Science Foundation of China

Western Light Foundation

Fujian Institute of Innovation, Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00698C

Reference53 articles.

1. Borates: A Rich Source for Optical Materials