Synthesis and reactivity of a terminal uranium(iv) sulfide supported by siloxide ligands-Reference-Cited by-同舟云学术

Synthesis and reactivity of a terminal uranium(iv) sulfide supported by siloxide ligands

Published:2016 Issue:9 Volume:7 Page:5846-5856
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Andrez Julie¹²³,Pécaut Jacques⁴⁵⁶⁷⁸,Scopelliti Rosario¹²³,Kefalidis Christos E.⁹¹⁰¹¹¹²¹³,Maron Laurent⁹¹⁰¹¹¹²¹³,Rosenzweig Michael W.¹⁴¹⁵¹⁶¹⁷¹⁸,Meyer Karsten¹⁴¹⁵¹⁶¹⁷¹⁸,Mazzanti Marinella¹²³

Affiliation:

1. Institut des Sciences et Ingénierie Chimiques Ecole Polytechnique Fédérale de Lausanne (EPFL)

2. 1015 Lausanne

3. Switzerland

4. Univ. Grenoble Alpes

5. INAC-SyMMES

6. RICC

7. F-38000 Grenoble

8. France

9. Université de Toulouse et CNRS INSA

10. UPS

11. CNRS

12. UMR 5215

13. LPCNO

14. Department of Chemistry and Pharmacy

15. Inorganic Chemistry

16. Friedrich-Alexander University Erlangen-Nürnberg

17. 91058 Erlangen

18. Germany

Abstract

The S-transfer reaction from Ph₃PS to the tetrasiloxide U(iii) complex [U(OSi(O^tBu)₃)₄K] affords a stable U(iv) triply bonded terminal sulfide that can be protonated to yield a U(iv) doubly bonded terminal hydrosulfide.

Funder

École Polytechnique Fédérale de Lausanne

Agence Nationale de la Recherche

Swiss National Science Foundation

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC00675B

Reference77 articles.