Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds-Reference-Cited by-同舟云学术

Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds

Published:2020 Issue:38 Volume:11 Page:10449-10456
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Richers Casseday P.¹²³⁴⁵,Roediger Sven¹²³⁴⁵^ORCID,Laserna Victor¹²³⁴⁵,Hartwig John F.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of California

3. United States and Chemical Sciences Division

4. Lawrence Berkeley National Laboratory

5. Berkeley

Abstract

A series of diphosphine-ligated rhodium(i) alkoxo alkene complexes is reported and the migratory insertion of the alkene moiety into the rhodium–oxygen bond in these complexes was studied, revealing the effects of the ligand on the insertion process.

Funder

U.S. Department of Energy

Office of Science

Bayer-Stiftungen

Deutscher Akademischer Austauschdienst

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC04402D

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