Affiliation:
1. Lehrstuhl für Organische Chemie II, Ruhr-Universität Bochum, 44801 Bochum, Germany
Abstract
The ring-opening of a highly strained cyclopropene to a carbene proceeds via heavy-atom tunneling. This rearrangement is accelerated in the presence of H2O, ICF3 or BF3, resulting in a novel Lewis-acid catalyzed tunneling reaction.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Cited by
11 articles.
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