Selectivity control between Mizoroki–Heck and homo-coupling reactions for synthesising multinuclear metal complexes: unique addition effects of tertiary phosphines and O2-Reference-Cited by-同舟云学术

Selectivity control between Mizoroki–Heck and homo-coupling reactions for synthesising multinuclear metal complexes: unique addition effects of tertiary phosphines and O2

Published:2017 Issue:14 Volume:46 Page:4816-4823
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yamazaki Yasuomi¹²³⁴⁵,Ishitani Osamu¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Science and Engineering

3. Tokyo Institute of Technology

4. Tokyo

5. Japan

Abstract

Selectivity control between the Mizoroki–Heck and the homo-coupling reactions for synthesising multinuclear metal complexes could be achieved by using tertiary phosphines and air, which affected the particle size of Pd species as catalysts for the reactions.

Funder

Japan Society for the Promotion of Science

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00922D

Reference32 articles.

1. Architecture of supramolecular metal complexes for photocatalytic CO2 reduction

2. Photocatalytic CO2 reduction with high turnover frequency and selectivity of formic acid formation using Ru(II) multinuclear complexes