Z-scheme water splitting utilizing CuLi1/3Ti2/3O2 as a hydrogen-evolving photocatalyst with photo-response up to 600 nm

Author:

Yoshino Shunya1,Kurutach Tanya12,Liu Qingshan12,Yamanaka Toshiki12,Nozawa Shunsuke3,Kobayashi Makoto4ORCID,Kumagai Hiromu5ORCID,Kato Hideki1ORCID

Affiliation:

1. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan

2. Department of Applied Chemistry, Graduate School of Engineering, Tohoku University, Sendai 980-8579, Japan

3. Institute of Materials Structure Science, High Energy Accelerator Research Organization, Tsukuba 305-0801, Japan

4. Institute of Materials and Systems for Sustainability, Nagoya University, Nagoya 464-8601, Japan

5. Research Center for Advanced Science and Technology, The University of Tokyo, Tokyo 153-8904, Japan

Abstract

CuLi1/3Ti2/3O2 modified with Cr2O3/Ru, which can utilize longer wavelength light in comparison with SrTiO3:Rh, a representative H2-evolving component, was successfully applied to Z-scheme water splitting with BiVO4 and Co(bpy)33+/2+.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

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