Ring-closing metathesis of dialkenylcycloalkanes for the synthesis of fused bicycloalkanes and tricycloalkanes

Author:

Tu Yuyang1,Inagaki Yusuke1,Ohara Kazuaki2ORCID,Yamaguchi Kentaro2ORCID,Setaka Wataru1ORCID

Affiliation:

1. Division of Applied Chemistry, Faculty of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo 192-0397, Japan

2. Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, 1314-1 Shido, Sanuki, Kagawa 769-2193, Japan

Abstract

Ring-closing metathesis of dialkenylcycloalkane, followed by hydrogenation, afforded a mixture of bicycloalkanes and tricycloalkanes. This method can synthesize a mixture of disilabicycloalkanes with one differing alkyl side chain.

Funder

Japan Science and Technology Agency

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

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