Exploiting click-chemistry: backbone post-functionalisation of homoleptic gold(i) 1,2,3-triazole-5-ylidene complexes

Author:

Richter Leon F.1ORCID,Marques Fernanda2ORCID,Correia João D. G.2ORCID,Pöthig Alexander3ORCID,Kühn Fritz E.1ORCID

Affiliation:

1. Technical University of Munich, TUM School of Natural Sciences, Department of Chemistry and Catalysis Research Centre, Molecular Catalysis, Lichtenbergstr. 4, 85748, Garching bei München, Germany

2. Centro de Ciências e Tecnologias Nucleares and Departamento de Engenharia e Ciências Nucleares, Instituto Superior Técnico, Universidade de Lisboa, CTN, Estrada Nacional 10 (km 139, 7), 2695-066 Bobadela LRS, Portugal

3. Technical University of Munich, TUM School of Natural Sciences, Department of Chemistry; Catalysis Research Center, Lichtenbergstr. 4, 85748 Garching bei München, Germany

Abstract

A novel, highly active homoleptic azide-functionalised Au(i) bis-1,2,3-triazole-5-ylidene complex is synthesised and easily modified using click-chemistry protocols, while maintaining high antiproliferative activity in human cancer cells.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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