Enzyme-inspired catalysts with high activity and selectivity for oxidative polymerization of 2-phenylphenol-Reference-Cited by-同舟云学术

Enzyme-inspired catalysts with high activity and selectivity for oxidative polymerization of 2-phenylphenol

Published:2023 Issue:17 Volume:13 Page:4968-4977
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Nakano Akiyuki¹,Raut Vivek S.²,Asao Naoki³^ORCID,Ando Akane⁴,Fujisawa Kiyoshi⁴,Higashimura Hideyuki¹^ORCID

Affiliation:

1. Department of Applied Science, Graduate School of Science, Okayama University of Science, Okayama 700-0005, Japan

2. Research Initiative for Supra-Materials, Shinshu University, Ueda, Nagano 386-8567, Japan

3. Division of Chemistry and Materials, Graduate School of Science and Technology, Shinshu University, Ueda, Nagano 386-8567, Japan

4. Department of Chemistry, College of Science, Ibaraki University, Mito, Ibaraki 310-8512, Japan

Abstract

Enzyme-inspired copper catalysts with moderately bulky substituents can accelerate the oxidative polymerization of 2-phenylphenol and increase the Mn of regioregular poly(2-phenylphenylene oxide) showing ultra-low ε to form a freestanding film.

Funder

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D3CY00170A

Reference30 articles.

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2. Polymerization by oxidative coupling: Discovery and commercialization of PPO� and Noryl� resins

3. Polymerization by oxidative coupling. VI. Oxidation of o-cresol

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