Formate-driven catalysis and mechanism of an iridium–copper complex for selective aerobic oxidation of aromatic olefins in water-Reference-Cited by-同舟云学术

Formate-driven catalysis and mechanism of an iridium–copper complex for selective aerobic oxidation of aromatic olefins in water

Published:2021 Issue:16 Volume:12 Page:5796-5803
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Shimoyama Yoshihiro¹²³⁴^ORCID,Kitagawa Yasutaka⁵⁶⁷⁸⁴^ORCID,Ohgomori Yuji¹²³⁴,Kon Yoshihiro¹²³⁴⁹^ORCID,Hong Dachao¹²³⁴⁹^ORCID

Affiliation:

1. Interdisciplinary Research Center for Catalytic Chemistry

2. National Institute of Advanced Industrial Science and Technology (AIST)

3. Tsukuba

4. Japan

5. Department of Materials Engineering Science

6. Graduate School of Engineering Science

7. Osaka University

8. Toyonaka

9. Global Zero Emission Research Center

Abstract

A hetero-dinuclear Ir^III–Cu^II complex with two adjacent sites was employed as a catalyst for the aerobic oxidation of aromatic olefins driven by formate and promoted by a hydrophobic interaction in water.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06634F

Reference63 articles.

1. Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts

2. Dioxygen in Polyoxometalate Mediated Reactions

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5. Aerobic oxidations in flow: opportunities for the fine chemicals and pharmaceuticals industries

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