Fluorination promotes chalcogen bonding in crystalline solids
Author:
Affiliation:
1. Laboratory of Nanostructured Fluorinated Materials (NFMLab)
2. Department of Chemistry
3. Materials, and Chemical Engineering “Giulio Natta”
4. 20131 Milano
5. Italy
6. CleveTheoComp
7. Cleveland
8. USA
Abstract
Flurorine promotes the electrophilicity of sulfur to the point that chalcogen bond formation affects the crystal packing in the solid.
Funder
Fondazione Cariplo
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CE/C7CE01070B
Reference50 articles.
1. Naming Interactions from the Electrophilic Site
2. Halogen bonding and other σ-hole interactions: a perspective
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4. Bonding Matters
5. Aerogen Bonding Interaction: A New Supramolecular Force?
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