Synergistic bimetallic CuPd oxide alloy electrocatalyst for ammonia production from the electrochemical nitrate reaction

Author:

Jung Wonsang12,Jeong Jaewoo3,Chae Younghyun12,Lee Woong Hee1ORCID,Ko Young-Jin1,Chae Keun Hwa4ORCID,Oh Hyung-suk15ORCID,Lee Ung126ORCID,Lee Dong Ki1267ORCID,Min Byoung Koun168ORCID,Shin Hyeyoung9,Hwang Yun Jeong1011ORCID,Won Da Hye12ORCID

Affiliation:

1. Clean Energy Research Center, Korea Institute of Science and Technology (KIST), Seoul 02792, Republic of Korea

2. Division of Energy and Environmental Technology, KIST School, Korea University of Science and Technology (UST), Seoul 02792, Republic of Korea

3. Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea

4. Advanced Analysis Center, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea

5. KIST-SKKU Carbon-Neutral Research Center, Sungkyunkwan University, 2066 Seobu-ro, Jangan-gu, Suwon 16419, Republic of Korea

6. Graduate School of Energy and Environment (Green School), Korea University, Seoul 02841, Republic of Korea

7. Department of Chemical and Biomolecular Engineering, Yonsei-KIST Convergence Research Institute, Yonsei University, Seoul 03722, Republic of Korea

8. Clean Energy Institute, Korea Institute of Science and Technology (KIST), Seoul 02792, Republic of Korea

9. Graduate School of Energy Science and Technology (GEST), Chungnam National University, Daejeon 34134, Republic of Korea

10. Department of Chemistry, Seoul National University, Seoul 08826, Republic of Korea

11. Center for Nanoparticle Research, Institute for Basic Science (IBS), Seoul 08826, Republic of Korea

Abstract

Bimetallic CuPd oxide alloy electrocatalysts can promote selective ammonia production from the nitrate reduction reaction by accelerating the rate-determining hydrogenation of nitrite, which is a critical intermediate.

Funder

National Research Foundation of Korea

Seoul National University

Korea Institute of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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