Zinc-mediated allylation of carbon dioxide—the LiOAc effect-Reference-Cited by-同舟云学术

Zinc-mediated allylation of carbon dioxide—the LiOAc effect

Published:2015 Issue:1 Volume:2 Page:65-68
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Miao Bukeyan¹²³⁴,Ma Shengming⁵⁶⁷⁴²

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Process

2. Department of Chemistry

3. East China Normal University

4. P. R. China

5. State Key Laboratory of Organometallic Chemistry

6. Shanghai Institute of Organic Chemistry

7. Chinese Academy of Sciences

Abstract

A direct carboxylation reaction of allylic bromides mediated by zinc powder with 1 atm of CO₂ provided by a balloon has been developed. The reaction occurred smoothly at room temperature in the presence of LiOAc with an excellent branched regioselectivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/QO/C4QO00300D

Reference21 articles.

1. Transition Metal Catalyzed Reactions of Carbon Dioxide and Other Heterocumulenes

2. Transformation of Carbon Dioxide

3. Utilisation of CO2 as a chemical feedstock: opportunities and challenges

4. Metal-Catalyzed Carboxylation of Organometallic Reagents with Carbon Dioxide

5. Recent developments in carbon dioxide utilization under mild conditions

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