Neutron scattering study of polyamorphic THF·17(H<sub>2</sub>O) – toward a generalized picture of amorphous states and structures derived from clathrate hydrates-Reference-Cited by-同舟云学术

Neutron scattering study of polyamorphic THF·17(H₂O) – toward a generalized picture of amorphous states and structures derived from clathrate hydrates

Published:2023 Issue:21 Volume:25 Page:14981-14991
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Brant Carvalho Paulo H. B.¹^ORCID,Ivanov Mikhail¹^ORCID,Andersson Ove²^ORCID,Loerting Thomas³^ORCID,Bauer Marion³,Tulk Chris A.⁴,Haberl Bianca⁴^ORCID,Daemen Luke L.⁴,Molaison Jamie J.⁴^ORCID,Amann-Winkel Katrin³^ORCID,Lyubartsev Alexander P.¹^ORCID,Bull Craig L.⁵⁶^ORCID,Funnell Nicholas P.⁵^ORCID,Häussermann Ulrich¹^ORCID

Affiliation:

1. Department of Materials and Environmental Chemistry, Stockholm University, SE-10691 Stockholm, Sweden

2. Department of Physics, Umeå University, SE-90187 Umeå, Sweden

3. Institute of Physical Chemistry, University of Innsbruck, A-6020 Innsbruck, Austria

4. Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA

5. ISIS Neutron and Muon Source, Rutherford Appleton Laboratory, Didcot, Oxon, OX11 7XN, UK

6. School of Chemistry, University of Edinburgh, David Brewster Road, Edinburgh EH9 3FJ, Scotland, UK

Abstract

Neutron scattering and simulation unveil amorphous clathrate hydrate structures. THF·17(H2O) yields three amorphs under high pressure and low temperature, resembling amorphous ice. THF and water's local structure is shaped by guest–host interactions.

Funder

Stiftelsen för Strategisk Forskning

U.S. Department of Energy

ISIS Neutron and Muon Source

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP00539A

Reference55 articles.

1. E. D. S.Jr. and C. A.Koh , Clathrate Hydrates of Natural Gases , CRC Press , 2007