Photoinduced HBr-catalyzed C–Si bond cleavage of benzylsilanes and their subsequent oxidation into benzoic acids with air as the terminal oxidant-Reference-Cited by-同舟云学术

Photoinduced HBr-catalyzed C–Si bond cleavage of benzylsilanes and their subsequent oxidation into benzoic acids with air as the terminal oxidant

Published:2014 Issue:10 Volume:1 Page:1201-1204
ISSN:2052-4129
Container-title:Org. Chem. Front.
language:en
Short-container-title:Org. Chem. Front.

Author:

Sun Jing¹²³⁴⁵,Wang Yu⁶⁷⁸²³,Han Liqiong¹²³,Xu Dawen¹²³,Chen Yiyong¹²³,Peng Xinhua⁴⁵⁹,Guo Hao¹²³¹⁰¹¹

Affiliation:

1. Department of Chemistry

2. Fudan University

3. Shanghai, P. R. China

4. School of Chemical Engineering

5. Nanjing University of Science and Technology

6. Department of Head and Neck Surgery

7. Fudan University Shanghai Cancer Center; Department of Oncology

8. Shanghai Medical College

9. Nanjing, P. R. China

10. Key Laboratory of Organofluorine Chemistry

11. Shanghai Institute of Organic Chemistry

Abstract

A photoinduced highly efficient C–Si bond cleavage reaction of benzylsilanes under the catalysis of HBr was developed. The in situ generated benzyl radical intermediates were aerobically oxidized into benzoic acids highly chemoselectively.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/QO/C4QO00229F

Reference28 articles.

1. Modern Strategies in Electroorganic Synthesis

2. Silperisone: A Centrally Acting Muscle Relaxant

3. Silatranes: a review on their synthesis, structure, reactivity and applications

4. The recent synthesis and application of silicon-stereogenic silanes: A renewed and significant challenge in asymmetric synthesis

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