Expanding and quantifying the crystal chemistry of the flexible ligand 15aneN5

Author:

Shircliff Anthony D.1,Allbritton Elisabeth M. A.1,Davilla Dustin J.1,Gorbet Michael-Joseph1,Jones Donald G.1,Tresp David S.1,Allen Michael B.1ORCID,Shrestha Alina1,Burgess Gwendolyn E.1,Eze John I.1,Fernandez Andrea T.1,Ramirez Daniel1,Shoff Kody J.1,Crispin Garet G.1,Crone Sarah B.1,Flinn Michael1,Tran Tien1,Bryce Darby S.1,Bond Abbagale L.1,Shockey Dylan W.1,Oliver Allen G.2,Krause Jeanette A.3,Prior Timothy J.4,Hubin Timothy J.1ORCID

Affiliation:

1. Department of Chemistry and Physics, Southwestern Oklahoma State University, 100 Campus Drive, Weatherford, OK, USA

2. Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN, USA

3. Department of Chemistry, University of Cincinnati, Cincinnati, OH, USA

4. Department of Chemistry, University of Hull, Cottingham Road, Kingston Upon Hull, HU6 7RX, UK

Abstract

15aneN5 is structurally characterized complexed to Cr3+, Mn3+, Fe3+, Co3+, and Cu2+ for the first time. Ru3+ complexation yields a Ru2+ diimine structure. A geometric factor quantifies the coordination geometry of the ligand in its complexes.

Funder

American Chemical Society Petroleum Research Fund

U.S. Department of Energy

Camille and Henry Dreyfus Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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