Facile synthesis and selected characteristics of two-dimensional material composed of iron sulfide and magnesium-based hydroxide layers (tochilinite)

Author:

Mikhlin Yuri L.1ORCID,Borisov Roman V.12ORCID,Likhatski Maxim N.1ORCID,Bayukov Oleg A.3,Knyazev Yuriy V.3ORCID,Zharkov Sergey M.32ORCID,Vorobyev Sergey A.1,Tomashevich Yevgeny V.1,Ivaneeva Anastasiya D.1ORCID,Karacharov Anton A.1,Karpov Denis V.1,Velikanov Dmitriy A.3,Rautskii Mikhail V.3,Smolyakov Dmitry A.3ORCID,Tarasov Anton S.32ORCID

Affiliation:

1. Institute of Chemistry and Chemical Technology, Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences, Akademgorodok, 50/24, Krasnoyarsk, 660036, Russia

2. Siberian Federal University, Svobodny av. 79, Krasnoyarsk, 660041, Russia

3. Kirensky Institute of Physics, Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50/38, Krasnoyarsk, 660036, Russia

Abstract

We report the reliable synthesis of 2D iron sulfide-magnesium hydroxide nanoflakes. The sulfide and hydroxide sheets assemble via opposite electric charges. Comparable amounts of high-spin Fe3+ and Fe2+ centers occur in the sulfide layers.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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