Copper(ii) triflate-mediated synthesis of functionalized silsesquioxanesviadehydrogenative coupling of POSS silanols with hydrosilanes-Reference-Cited by-同舟云学术

Copper(ii) triflate-mediated synthesis of functionalized silsesquioxanesviadehydrogenative coupling of POSS silanols with hydrosilanes

Published:2019 Issue:19 Volume:48 Page:6341-6346
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kaźmierczak Joanna¹²³⁴,Hreczycho Grzegorz¹²³⁴^ORCID

Affiliation:

1. Faculty of Chemistry

2. Adam Mickiewicz University in Poznań

3. 61-614 Poznań

4. Poland

Abstract

A novel, effective catalytic methodology for modification of silsesquioxanes is reported, which is based on dehydrogenative coupling between POSS silanols and commercially available hydrosilanes mediated by inexpensive Cu(OTf)₂.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01135H

Reference44 articles.

1. D. B. Cordes and P. D.Lickiss , in Applications of Polyhedral Oligomeric Silsesquioxanes , ed. C. Hartmann-Thompson , Springer , Netherlands, Dordrecht , 2011 , pp. 47–133

2. Polyhedral oligomeric silsesquioxanes (POSSs): an important building block for organic optoelectronic materials

3. A. R. Jennings , S. T.Iacono and J. M.Mabry , in Handbook of Sol-Gel Science and Technology , ed. L. Klein , M. Aparicio and A. Jitianu , Springer International Publishing , Cham , 2016 , pp. 1–24

4. Fluorinated Polyhedral Oligomeric Silsesquioxanes (F-POSS)

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