CAl<sub>11</sub><sup>−</sup>: a molecular rotor with a quasi-planar tetracoordinate carbon-Reference-Cited by-同舟云学术

CAl₁₁⁻: a molecular rotor with a quasi-planar tetracoordinate carbon

Published:2023 Issue:33 Volume:59 Page:4966-4969
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bai Li-Xia¹,Barroso Jorge²^ORCID,Orozco-Ic Mesías³^ORCID,Ortiz-Chi Filiberto⁴^ORCID,Guo Jin-Chang¹^ORCID,Merino Gabriel²^ORCID

Affiliation:

1. Nanocluster Laboratory, Institute of Molecular Science, Shanxi University, Taiyuan 030006, China

2. Departamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados, Unidad Mérida. Km 6 Antigua Carretera a Progreso. Apdo. Postal 73, Cordemex, 97310, Mérida, Yuc, Mexico

3. Department of Chemistry, Faculty of Science, University of Helsinki, P.O. Box 55, A. I. Virtasen aukio 1, FIN-00014, Helsinki, Finland

4. CONACYT-División Académica de Ciencias Básicas, Universidad Juárez Autónoma de Tabasco, Cunduacán 86690, Tabasco, Mexico

Abstract

The global minimum of CAl11− is formed by two stacked layers, one of them resembles the well-known planar tetracoordinate carbon CAl4 on top of a hexagonal Al@Al6 wheel. The CAl4 fragment rotates freely around the central axis with a negligible barrier.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shanxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC00855J

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