Nickel-catalysed diversification of phosphine ligands by formal substitution at phosphorus

Author:

Roediger Sven1ORCID,Leutenegger Sebastian U.1ORCID,Morandi Bill1ORCID

Affiliation:

1. Laboratorium für Organische Chemie, ETH Zürich, Vladimir-Prelog-Weg 3, HCI, 8093 Zürich, Switzerland

Abstract

Phosphine substituents can be exchanged by standard alkylation of a phosphine and a subsequent dearylation of the resulting phosphonium salt. A wide variety of alkyl groups can be introduced into both mono- and bidentate ligands using this method.

Funder

Eidgenössische Technische Hochschule Zürich

Fonds der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference73 articles.

1. J. F.Hartwig , Organotransition Metal Chemistry: From Bonding To Catalysis , University Science Books , Sausalito, CA, USA , 2010

2. Trends in the Usage of Bidentate Phosphines as Ligands in Nickel Catalysis

3. Phosphorus(iii) Ligands in Homogeneous Catalysis: Design and Synthesis , ed. P. C. J. Kamer and P. W. N. M. van Leeuwen , John Wiley & Sons, Ltd , Chichester, UK , 2012

4. E. I.Musina , A. S.Balueva and A. A.Karasik , in Organophosphorus Chemistry , ed. L. J. Higham , D. W. Allen and J. C. Tebby , Royal Society of Chemistry , 2021 , vol. 50 , pp. 37–114

5. Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3