Valorization of 2,5-furandicarboxylic acid. Diels–Alder reactions with benzyne

Author:

Serum Eric M.1234ORCID,Selvakumar Sermadurai5678ORCID,Zimmermann Nicolas910,Sibi Mukund P.1234ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. North Dakota State University

3. Fargo

4. USA

5. Department of Chemistry

6. Central University of Haryana

7. Mahendergarh-123031

8. India

9. Sigma Informatique

10. France

Abstract

Biomass-derived 2,5-furandicarboxylic acid was valorized by conversion to 1,4-naphthalenedicarboxylic acid via benzyne-cycloaddition and reductive aromatization in 66% overall yield (four steps).

Funder

National Science Foundation

Office of Experimental Program to Stimulate Competitive Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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