Valorization of 2,5-furandicarboxylic acid. Diels–Alder reactions with benzyne
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. North Dakota State University
3. Fargo
4. USA
5. Department of Chemistry
6. Central University of Haryana
7. Mahendergarh-123031
8. India
9. Sigma Informatique
10. France
Abstract
Biomass-derived 2,5-furandicarboxylic acid was valorized by conversion to 1,4-naphthalenedicarboxylic acid via benzyne-cycloaddition and reductive aromatization in 66% overall yield (four steps).
Funder
National Science Foundation
Office of Experimental Program to Stimulate Competitive Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/GC/C8GC00308D
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