The reactivity of acyl chlorides towards sodium phosphaethynolate, Na(OCP): a mechanistic case study-Reference-Cited by-同舟云学术

The reactivity of acyl chlorides towards sodium phosphaethynolate, Na(OCP): a mechanistic case study

Published:2016 Issue:9 Volume:7 Page:6125-6131
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Heift Dominikus¹²³⁴,Benkő Zoltán¹²³⁴⁵,Suter Riccardo¹²³⁴^ORCID,Verel René¹²³⁴,Grützmacher Hansjörg¹²³⁴⁶^ORCID

Affiliation:

1. Department of Chemistry and Applied Biosciences

2. ETH Zurich

3. CH-8093 Zurich

4. Switzerland

5. Budapest University of Technology and Economics

6. Lehn Institute of Functional Materials (LIFM)

Abstract

The phosphaethynolate anion (OCP)⁻ has three different functions in the reaction with 2,4,6-trimethylbenzoyl chloride (MesCOCl): it acts as a nucleophile, as an en-component in [2 + 2] cycloadditions and as a formal P⁻ transfer reagent.

Funder

Swiss National Science Foundation

Eidgenössische Technische Hochschule Zürich

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC01269H

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