Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes-Reference-Cited by-同舟云学术

Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes

Published:2022 Issue:59 Volume:58 Page:8206-8209
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Vicente Rubén¹^ORCID,Tudela Eva¹,Rodríguez Miguel A.²,Suárez-Sobrino Ángel L.¹,Ballesteros Alfredo¹^ORCID

Affiliation:

1. Departamento de Química Orgánica e Inorgánica and Instituto Universitario de Química Organometálica “Enrique Moles”, Universidad de Oviedo C/Julian Clavería 8, 33006, Oviedo, Spain

2. Departamento de Química, Centro de Investigación en Síntesis Química, Universidad de la Rioja, 26006, Logroño, Spain

Abstract

The synthesis of particular cyclopropane-tethered 1,5-enynes, namely 6-alkynyl-4-alkylidenebicyclo[3.1.0]hex-2-enes, enabled the discovery of unprecedented gold-catalyzed rearrangment to indenes.

Funder

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC02869G

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