A flexible iron(ii) complex in which zero-field splitting is resistant to structural variation-Reference-Cited by-同舟云学术

A flexible iron(ii) complex in which zero-field splitting is resistant to structural variation

Published:2016 Issue:1 Volume:7 Page:416-423
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zadrozny Joseph M.¹²³⁴,Greer Samuel M.⁵⁶⁷⁴⁸,Hill Stephen⁸⁷⁴⁹⁶,Freedman Danna E.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Northwestern University

3. Evanston

4. USA

5. Department of Chemistry and Biochemistry

6. Florida State University

7. Tallahassee

8. National High Magnetic Field Laboratory

9. Department of Physics

Abstract

The zero-field splitting parameters D and E in the iron(ii) complex [Fe(C₃S₅)₂]²⁻ are shown to be remarkably resistant to a twist of the inter-ligand dihedral angle (θ_d) from 90 to 70°.

Funder

Air Force Office of Scientific Research

Division of Materials Research

Northwestern University

Illinois Department of Commerce and Economic Opportunity

Division of Graduate Education

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC02477C

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