Revealing the effect of grain boundary segregation on Li ion transport in polycrystalline anti-perovskite Li3ClO: a phase field study-Reference-Cited by-同舟云学术

Revealing the effect of grain boundary segregation on Li ion transport in polycrystalline anti-perovskite Li3ClO: a phase field study

Published:2020 Issue:5 Volume:22 Page:3030-3036
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Shen Kun¹²³⁴^ORCID,Wang Yixuan¹²³⁴,Zhang Jun⁵⁶⁷³⁴,Zong Yi⁵⁶⁷³⁴,Li Gengwei¹²³⁴,Zhao Changchun¹²³⁴^ORCID,Chen Hao⁵⁶⁷³⁴

Affiliation:

1. School of Science

2. China University of Geosciences

3. Beijing

4. China

5. Key Laboratory of Advanced Materials of Ministry of Education

6. School of Materials Science and Engineering

7. Tsinghua University

Abstract

Phase field calculated effective diffusivity D_eff of Li vacancy in anti-perovskite Li₃OCl is shown as a function of average grain sizes. Li vacancy segregation reinforces the negative contribution of grain boundaries on the overall Li diffusion.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP06055C

Reference31 articles.

1. A review of conduction phenomena in Li-ion batteries

2. Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction

3. Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries

4. Challenges for Rechargeable Li Batteries

5. Ceramic separators based on Li+-conducting inorganic electrolyte for high-performance lithium-ion batteries with enhanced safety

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