A practical deca-gram scale ring expansion of (R)-(−)-carvone to (R)-(+)-3-methyl-6-isopropenyl-cyclohept-3-enone-1
Author:
Affiliation:
1. Departamento de Química
2. Universidade Federal de São Carlos
3. São Carlos – SP
4. Brazil
5. Department of Chemistry
6. University of Cambridge
7. Cambridge
8. UK
Abstract
A route to enantiopure (R)-(+)-3-methyl-6-isopropenyl-cyclohept-3-enone-1, an intermediate for terpenoids, has been developed and includes a highly chemo- and regioselective Tiffeneau–Demjanov reaction.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB00525F
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1. The Synthesis of Seven-Membered Rings in Natural Products
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