Binding orientation and reactivity of alkyl α,ω-dibromides in water-soluble cavitands-Reference-Cited by-同舟云学术

Binding orientation and reactivity of alkyl α,ω-dibromides in water-soluble cavitands

Published:2019 Issue:21 Volume:17 Page:5279-5282
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Angamuthu Venkatachalam¹²³⁴,Petroselli Manuel¹²³⁴^ORCID,Rahman Faiz-Ur¹²³⁴^ORCID,Yu Yang¹²³⁴^ORCID,Rebek Julius¹²³⁴⁵

Affiliation:

1. Center for Supramolecular Chemistry and Catalysis and Department of Chemistry

2. Shanghai University

3. Shanghai 200444

4. P. R. China

5. The Skaggs Institute for Chemical Biology and Department of Chemistry

Abstract

Host–guest complexation of α,ω-dibromides showed rabid tumbling conformation on NMR timescales and afforded mono hydroxyl bromides after hydrolysis in D₂O.

Funder

National Science Foundation

National Natural Science Foundation of China

Shanghai University

Shanghai Municipal Education Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB01018A

Reference44 articles.

1. Compressed Corannulene in a Molecular Cage

2. Corannulen komprimiert in einem molekularen Käfig

3. The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations

4. Enzyme-like Control of Carbocation Deprotonation Regioselectivity in Supramolecular Catalysis of the Nazarov Cyclization

5. Supramolecular Catalysis of a Unimolecular Transformation: Aza-Cope Rearrangement within a Self-Assembled Host

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