Theoretical insights into photo-induced electron transfer at BiOX (X = F, Cl, Br, I) (001) surfaces and interfaces

Author:

Li Tan123,Zhang Xiaochao123ORCID,Zhang Changming123,Li Rui123,Liu Jianxin123,Lv Rui123,Zhang Hui456,Han Peide723,Fan Caimei123,Zheng Zhanfeng89ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering, Taiyuan University of Technology

2. Taiyuan 030024

3. P. R. China

4. Particle Technology Research Centre, Department of Chemical and Biochemical Engineering, The University of Western Ontario

5. London

6. Canada

7. College of Materials Science and Engineering, Taiyuan University of Technology

8. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences

9. China

Abstract

Self-endowed internal electric field (IEF) of BiOX crystals affects the effective electrons through O → Bi → X → X → Bi → O path to BiOX(001) interfaces with the key roles of X as “Magpie Bridge”.

Funder

Natural Science Foundation of Shanxi Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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