The role of dispersion type metal⋯π interaction in the enantiotropic phase transition of two polymorphs of tris-(thienyl)bismuthine-Reference-Cited by-同舟云学术

The role of dispersion type metal⋯π interaction in the enantiotropic phase transition of two polymorphs of tris-(thienyl)bismuthine

Published:2017 Issue:39 Volume:46 Page:13492-13501
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Preda A. M.¹²³⁴⁵,Schneider W. B.¹²³⁴⁵,Schaarschmidt D.¹²³⁶⁵,Lang H.¹²³⁶⁵,Mertens L.¹²³⁴⁵,Auer A. A.⁷⁸⁹,Mehring M.¹²³⁴⁵^ORCID

Affiliation:

1. Technische Universität Chemnitz

2. Fakultät für Naturwissenschaften

3. Institut für Chemie

4. Professur Koordinationschemie

5. 09107 Chemnitz

6. Professur Anorganische Chemie

7. Max-Planck-Institut für Chemische Energiekonversion

8. 45470 Mülheim an der Ruhr

9. Germany

Abstract

Bi(2-C₄H₃S)₃ shows an enantiotropic phase transition that is dominated by London dispersion forces. DFT calculations on model compounds were carried out in order to investigate the competition between Bi⋯S and Bi⋯π heteroarene interaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02567J

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