Synthesis of paracyclophanes with planar and central chirality: kinetic resolution of [2.2]paracyclophane aldimines via palladium-catalyzed addition of arylboronic acids-Reference-Cited by-同舟云学术

Synthesis of paracyclophanes with planar and central chirality: kinetic resolution of [2.2]paracyclophane aldimines via palladium-catalyzed addition of arylboronic acids

Published:2019 Issue:24 Volume:6 Page:3956-3960
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhao Yang¹²³⁴⁵^ORCID,Wang Han¹²³⁴⁵,Wu Bo¹²³⁴⁵,Zhou Yong-Gui¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Catalysis

2. Dalian Institute of Chemical Physics

3. Chinese Academy of Sciences

4. Dalian 116023

5. P. R. China

Abstract

Kinetic resolution of [2.2]paracyclophane aldimines was achieved through a palladium-catalyzed enantioselective arylation, providing access to chiral paracyclophanes with planar and central chirality as well as the recovered chiral aldimines.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO01011D

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2. The crystal and molecular structure of 1,1,2,2,9,9,10,10-octafluoro-[2,2]paracyclophane and a reinvestigation of the structure of [2,2]paracyclophane