Ratcheting rotation or speedy spinning: EPR and dynamics of Sc3C2@C80-Reference-Cited by-同舟云学术

Ratcheting rotation or speedy spinning: EPR and dynamics of Sc3C2@C80

Published:2017 Issue:64 Volume:53 Page:8992-8995
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Roukala Juho¹²³⁴^ORCID,Straka Michal⁵⁶⁷⁸^ORCID,Taubert Stefan⁹¹⁰¹¹⁴^ORCID,Vaara Juha¹²³⁴^ORCID,Lantto Perttu¹²³⁴^ORCID

Affiliation:

1. NMR Research Unit

2. University of Oulu

3. FI-90014 Oulu

4. Finland

5. Institute of Organic Chemistry and Biochemistry

6. Flemingovo nam. 2

7. Prague

8. Czech Republic

9. Department of Chemistry

10. University of Helsinki

11. FI-00014 Helsinki

Abstract

First principles modelling graphically explains how changes in the Sc-trimer motion cause the curious temperature dependence of Sc₃C₂@C₈₀ EPR spectra.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC04695B

Reference28 articles.

1. Fullerenes with metals inside

2. Chemical Reactivity of Sc3N@C80 and La2@C80

3. Endohedral Fullerenes

4. Current status and future developments of endohedral metallofullerenes

5. In vivo studies of fullerene-based materials using endohedral metallofullerene radiotracers

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